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Carbon monoxide is inert - not flammable.
Your thinking dioxide... monoxide does burn... I use it in the shop as a cheap foundry fuel... aslong as you evacuate the co2 it burns great... never had it explode though... not sure it would carbon-oxygen bonds dont have the energy and aren't as weak as carbon-hydrogen bonds(where acetylene gets it explosive power)...
Wow. You learn something new every day. Thanks.